Welcome to the forum! We have a 25.2 also, and are quite happy after about 60 nights in it.
This is a great place to bring your questions, from the simple to the complex.
I don't believe there is any way to connect either radio to either TV. Your dealer will likely be clueless on this, but the Thor warranty guys would be the ones to ask.
I think we need to stop calling it "working from home" and start calling it "living at work!"