On your RV, as is normally the case, coach battery charging from the alternator is handled through the emergency start solenoid. Depending on what and where Thor installed it, you will have either a BIM or a IRD/Trombetta solenoid. It may be in the battery compartment or it may be hidden somewhere under the hood or somewhere else. Can't tell you exactly where to look, but I can point you in the general direction. If you have the BIM, it's likely wired backwards from the factory and won't properly charge the coach batteries from the alternator
If you NEED to run the inverter while driving, you will probably need to run the generator periodically to recharge the coach batteries. If you do not absolutely need to use the inverter, switch it off as much as you can. Usual reasons for keeping it on would be a 120 VAC fridge or you need 120 VAC for plugged in items like a computer.
There is also a Facebook group for Thor Quantum owners. You'll find a concentration of model-specific information among its members.